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Convert mass and moles using m = n × M

Quantitative chemistryConcentration of solutions

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What unit appears after cancelation when calculating n = m ÷ M correctly?

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The unit mol appears after cancelation, since grams cancel with g in g mol-1 leaving mol.

Key concepts

What you'll likely be quizzed about

Definition of mole and molar mass

The mole represents a fixed number of particles: 6.02 × 10^23 entities (Avogadro's number). Molar mass (M) equals the mass of one mole of a substance and uses units of g mol-1. Elemental molar mass uses relative atomic mass values from the periodic table; compound molar mass equals the sum of the atomic masses of its constituent atoms.

Core formula and algebraic rearrangement

The core equation m = n × M links mass (m), amount in moles (n) and molar mass (M). Rearrangement yields n = m ÷ M for mass to moles and m = n × M for moles to mass. Correct algebraic manipulation allows accurate conversion in both directions.

Unit handling and common unit conversions

Mass must be in grams when using molar mass in g mol-1. Kilograms and milligrams require conversion to grams before substitution. Amount (n) uses the unit mol. Molar mass uses g mol-1; cancelation of units in n = m ÷ M leaves mol as the resulting unit. Incorrect units cause numerically wrong answers.

Procedure: step-by-step conversion

To convert mass to moles: (1) Convert mass to grams if necessary, (2) calculate the molar mass of the substance from atomic masses, (3) substitute into n = m ÷ M and compute, remembering units. To convert moles to mass: multiply the number of moles by the molar mass using m = n × M. Clear intermediate steps reduce arithmetic errors.

Limiting factors and significant figures

Molar masses from the periodic table are typically quoted to two decimal places; the final answer should reflect the precision of input data. Extremely large or small masses may require expression in scientific notation. The mole concept applies to atoms, ions and molecules alike; the same method applies whether the substance is an element or a compound.

Key notes

Important points to keep in mind

Always convert mass to grams when using molar mass in g mol-1.

Use n = m ÷ M to find moles and m = n × M to find mass.

Calculate molar mass by summing atomic masses from the periodic table.

Check units cancel correctly: g ÷ (g mol-1) gives mol.

Convert kg → g by ×1000 and mg → g by ÷1000 before calculation.

Keep consistent significant figures; final answer reflects least precise input.

Use scientific notation for very large or very small masses or mole amounts.

Label answers with correct units: mass in g, amount in mol.

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